Adsorption study of various dyes on activated carbon fe3o4 magnetic nano composite 259 c. Comparison between pseudofirst order and pseudosecond order kinetic models for bb66 dye adsorption on clay at different initial concentration and 30 o c. Chemical activation using orthophosphoric acid h3po4 was employed for the preparation of activated carbon. Adsorption studies were performed by batch experiments. In recent literature, activated carbons from different origins have been used for dye removal 2530. In this work, removal of congo red, crystal violet, turquoise blue, reactive black 5, and malachite green onto. The oxygencontaining groups of activated carbon prepared from cw play an important role in dyes ions adsorption onto activated carbon prepared from cw. Liquid phase adsorption experiments were conducted to study the removal of methylene blue mb, malachite green mg and congo red cr dyes from aqueous solution using granular activated carbon gac.
Despite the frequent use of adsorption in wastewater treatment systems, commercially available activated carbon remains an expensive material. The effect of ph, initial dye concentration, adsorbent dose, the particle size of, agitation speed, temperature, and contact time was explored. Preparation and characterization of activated carbon from. Adsorption on activated carbons has been proven to be very effective in removing dyes from aqueous solutions. An alkaliacitvated method was explored to synthesize activated carbon nanotubes cntsa with a high specific surface area ssa, and a large number of mesopores. The carbon in this case is used to remove a portion of the remaining dissolved organic matter. Experimental results indicated that acbpv adsorbent exhibited highselectivity adsorption and efficiency for anionic dyes. Pdf removal of dyes from wastewater using adsorption. As proved by many researchers, removal of dyes by activated carbon is economically favorable and technically easier. Adsorption of methylene blue in water onto activated carbon by. Oct 31, 2017 tseng rl, wu fc, juang rs 2003 liquidphase adsorption of dyes and phenols using pinewoodbased activated carbons. Adsorption of cationic dyes on activated carbon obtained from waste.
The adsorption of three acidic dyes, acid blue 80 ab80, acid red 114 ar114, and acid yellow 117 ay117 onto activated carbon, filtrasorb 400, has been studied. The equilibrium adsorption data were analyzed using two widely. Kinetic data obtained in this way were tested according to pseudofirst order. Processes that utilize this type of carbon include. Insitu uvvisible spectroscopic study on the adsorption. Thus, the adsorption phenomenon was suggested as a chemical process. Alkaim a, a department of chemistry, college of sciences for women, babylon university, hilla, iraq b department of chemistry, college of sciences, babylon university, hilla, iraq. Box 150459, zarqa, jordan b school of chemistry and chemical engineering, queens university belfast, david keir building, stranmillis. Adsorption of disperse dye by powdered activated carbon. It was suggested that the pseudo second order adsorption mechanism was predominant for the sorption of the reactive dyes onto the tannery sludge based carbon.
Adsorption of reactive dyes from aqueous solutions by. The production of dye is increased rapidly due to the development of various industries. Removal of methylene blue from wastewater by adsorption onto. Effect of solution ph, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon yahya s. Adsorption isotherm of the three dyes obeyed freundlich isotherm modal. Removal of malachite green dyes by adsorption onto activated. Comparisons of azo dye adsorptions onto activated carbon. The purpose of this laboratory study is to investigate the effectiveness of powered activated carbon pac on the removal of chemical oxygen demand cod and color of disperse dye and the effect of pac particle size on the treatment efficiency. Adsorption through granular activated carbon was found to be very effective for the removal of the different dyes considered, where the percent dye removal was 96. Characterization and study of adsorption of methyleneblue dye using activated carbon a thesis submitted to the. Experimental data on optical density of blank solutions of different concentrations ranging from 10 to 100 mgl and optical density of solutions after adsorption on activated carbon samples were taken and analyzed. The work deals with the adsorption of two dyes namely food red 17 fr17 and methyl violet mv onto a sludge derived activated carbon sdac. Comparative study on the adsorption kinetics and thermodynamics of dyes onto acid activated low cost carbon.
Adsorption isotherms, kinetics, thermodynamics and. The adsorption process is being extensively used for the removal of dyes from synthetic dyehouse effluents by various researchers. The adsorption of dyes is favored by mesoporous 2 to 50 nm carbon because the molecular size of the dyes is larger than the micropores. It is therefore extremely important to treat such effluents prior to discharge. A dye adsorption capacity of activated carbon for the ro16 is 147. The fritzschlunder model best describes the uptake of grl and dy 12 dye, which implies that the adsorption of textiles dyes in this study onto coconut husk activated carbon is heterogeneous with multilayers. Removal of dyes from aqueous solution using activated. Results obtained shows that the acid activated carbon serves as the best activated carbon with highest adsorption value of 99. Rhodamine b dyes adsorption on palm kernel shell based. The basic sample obtained by thermal treatment under h 2 flow at 700 c is the best material for the adsorption of most of the dyes tested. In the past years, several investigations have been reported the removal of dyes using activated carbons. Enhanced adsorptive removal of methyl orange and methylene. Kinetics and equilibrium study for the adsorption of textile dyes on.
In addition to the diffusion into pores, the dye molecules can interact with the surface charge of the activated carbon rodriguez et al. Kinetics and equilibrium study for the adsorption of. Pdf adsorption of reactive dyes on activated carbon developed. Pdf dye adsorbent by activated carbon researchgate. Pdf adsorption of dyes as a remediation technique for dyeloaded wastewater remains an area of interest. Activated carbon adsorption processes are often used for this purpose due to their versatility, efficiency and low operating costs matta et al. The fritzschlunder model best describes the uptake of grl and dy 12 dye, which implies that the adsorption of textiles dyes in this study onto coconut husk activated carbon is. Commercial activated carbon, coir pith activated carbon, adsorption, aqueous dye solution. The carbon embedded in conducting polymers matrix show better adsorptive properties than activated carbon. Adsorption of textile dyes using an activated carbon and. Adsorption behavior of the modified activated carbon from aqueous solution was investigated by varying the parameters such as ph, contact time and amaranth concentration, and the optimum adsorption ph was 1.
The adsorption process uses forces of molecular attraction to bind soluble and gaseous chemicals to a surface. The equilibrium data were evaluated using langmuir, freundlich, temkin and fritzschlunder isotherms. Nonbiodegradable nature of pollutants and their removal in. Calibration curves were plotted and the amount of dye adsorbed was calculated. The removal of dye could be carried out by using activated carbon through adsorption process. Therefore, extensive study on adsorption of these classes of pollutants from water bodies is being carried out. Application of film surface and film pore diffusion models. A study of ability of adsorption of some dyes on activated carbon. Activated carbon treatment of waste water is usually thought of as a polishing process for water that has already received normal biological treatment. Kinetic study of the adsorption of dyes onto activated carbon. The resulting cntsa were used as an adsorbent material for removal of anionic and cationic dyes in aqueous solutions. Adsorption of dye eosin from an aqueous solution on two. In this study, high adsorption capacity of activated carbon and unique properties of cryogels are combined and activated carbon embedded, composite phema cryogel discs are sythesized for the removal of selected dyes.
The values of percent removal and kd for two dyes by activated carbon were calculated. The adsorp tion process on activated carbon was mainly controlled by intraparticle diffusion mechanism. The results also showed that the cop can act as activated carbon for removal of dyes. The experimental findings showed that the removal efficiencies of three dyes onto activated carbon were maximum at the initial. Acid blue 74 from aqueous solution onto the activated carbon cloth acc has been investigated. However, activated carbon is still considered to be expensive and current research is focused on the development of lowcost adsorbents for this purpose. Sivakumar 3 1department of chemistry, alameen engineering college, erode, tamilnadu, india. Carbon used for adsorption is usually treated activated to make it very porous. Coconutbased activated carbon fibers for efficient. In fact, a teaspoon of activated carbon has more surface area than a football field. The kinetics of the adsorption systems were evaluated by pseudo firstorder and modified pseudo firstorder models. Pdf adsorption of basic dyes on granular activated. Therefore, there is a need to produce acti vated carbon from cheaper and readily available materi als.
The most widely used adsorbent is commercially available activated carbon. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon aseel m. Therefore, the removal of dyes through activated carbon adsorption is very effective. Experimental results indicated that cntsa have excellent adsorption capacity for methyl orange 149 mgg and. Adsorption study of various dyes on activated carbon fe o. Bio automation, 2015, 192, 187206 187 adsorption of direct of yellow arle dye by activated carbon of shell of coconut palm. This study investigates the potential use of activated carbon prepared from coffee waste cw as an adsorbent for the removal of congo red dye from aqueous solution. For this purpose, activated carbon was prepared via chemical treatment of palm leaf wastes with sulfuric acid h 2 so 4, phosphoric acid h 3 po 4, and nitric acid hno 3. Secondorder kinetic models fitted better to the equilibrium data of three dyes.
Adsorption characteristics of a low cost activated carbon. Selective adsorption of anionic dye from solutions by. Competitive adsorption of dyes congo red, methylene blue. Physicochemical and adsorption studies of activated. Original article kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon aseel m. Adsorption is a process where a solid is used for removing a soluble substance from the water. Fixedbed or expandedbed adsorption movingbed adsorption. Activated carbon prepared from seed tamarindus indica was utilized for the removal of orange g and safranin o dyes from aqueous solution. Adsorption of direct of yellow arle dye by activated.
The ph 23 was found suitable for maximum removal of ro16. The adsorbent has been studied as a function of contact time, temperature, ph and initial dye concentration by batch experiments. Adsorption of anionic and cationic dyes on activated. Removal of dye eosin on two different samples of activated carbon by static batch method was studied. Four models for predicting the multicomponent equilibrium sorption isotherms have been compared in order to. Abstract this study was designed to investigate the removal of reactive violet 48 from wastewater using commercial activated carbon and coir pith activated carbon. Effect of solution ph, ionic strength, and temperature on. Dyes are used extensively in various industries such as textiles. Dye and its removal from aqueous solution by adsorption. Activated carbon is produced specifically so as to achieve a very big internal surface between 500 1500 m 2 g. Adsorption of reactive dyes from aqueous solutions by tannery. Preparation and characterization of activated carbon from thevetia peruviana for the removal of dyes from textile waste water j.
Activated carbon is one of the most studied materials for the adsorption of textile dyes. Diffusional effects on kinetics and equilibrium states. The removal of each dye has been followed by insitu uvvisible spectroscopic method using the socalled scanning kinetics technique. Langmuir isotherm models applied to the multicomponent. Furthermore, activated carbon is used as adsorbent for dye removal from wastewater. Adsorption characteristics of a low cost activated carbon for. An experimental analysis of adsorbent properties is. The present state of the art on the application of adsorption in the removal of dyes from aqueous solution is presented in this paper. Major drawback of activated carbon is that it is a very expensive material and small. Pdf adsorption of reactive dyes by palm kernel shell.
The equilibrium was found to be nearly 60 min when the maximum dye adsorption capacity was reached. Dec 18, 2017 experimental results indicated that acbpv adsorbent exhibited highselectivity adsorption and efficiency for anionic dyes. The adsorption behaviors of three reactive dyes reactive red 23, reactive blue 171 and reactive blue 4 onto this biomass activated carbon were investigated in batch systems. It has more useful surface area per gram than any other material available for physical adsorption. The adsorption equilibrium of two azo dyes on activated carbon and silicon carbide nanoparticles loaded on activated carbon was investigated using the langmuir, freundlich, and temkin isotherms. Removal of methylene blue from wastewater by adsorption. This warrants for the removal of the dyes from effluents. Adsorption, precipitation, oxidation, etc are well known methods for removal of dyes from effluents and activated carbon adsorption has been most common. Lowcost adsorbents include natural, agricultural and. Adsorption of basic dyes on granular activated carbon and natural zeolite article pdf available in water research 3514. Pdf removal of dye by adsorption onto activated carbons.
Removal of malachite green dyes by adsorption onto. Alkaim a, a department of chemistry, college of sciences for women, babylon university, hilla, iraq b department of chemistry, college of sciences, babylon university, hilla, iraq received 29 june 20. Pdf competitive adsorption of dyes onto granular activated. Adsorption of reactive dyes on activated carbon developed. Comparative studies of the adsorption of direct dye on activated. The adsorption process of activated carbon, however, is prohibitively expensive, which limits its application. The removal of methylene blue by activated carbon of corn husk by zncl 2 activation was investigated in the present study. International journal of physics sciences, 21, 1017. Modeling adsorption of organic compounds on activated carbon.
Characterization and study of adsorption of methyleneblue dye using activated carbon a thesis submitted to the national institute of technology, rourkela in partial fulfilment of the requirements of bachelor of technology chemical engineering by debi prasad samal roll no. Dye adsorption capacities of activated carbon were 59. Removal of azo dyes violet b and violet 5r from aqueous. Preparation and characterization of impregnated activated carbon from palm kernel shell and coconut shell for co2 capture. Taking into consideration that samples ac6 to ac8 have the best performances for dye adsorption, and that these samples have practically no oxygencontaining groups, as can be seen in the tpd results, the interaction of the reactive dyes with the surface of the activated carbon materials is expected to be mainly between the oxygenfree lewis. As well as being highly efficient, activated carbon is an economically accessible material because it can be prepared using vegetable residues which are rich in cellulose and lignin. Therefore, the adsorption time was fixed at 60 min in subsequent adsorption experiments. Adsorption of disperse dye by powdered activated carbon lin. Four batch systems were applied to study the adsorption by activated carbon of methylene blue, methyl orange, crystal violet and rhodamine b from aqueous solution. In order to improve the adsorption capability of the raw carbon, it is subjected to various suitable chemical treatments. Nonbiodegradable nature of pollutants and their removal in the present generation is a great challenge. It was shown that the surface chemistry of the activated carbon plays a key role in dye adsorption performance.
Activated carbon was prepared from enteromorpha prolifera by zinc chloride activation. Carbon based sorbents show excellent adsorption properties for a considerable number of synthetic dyes. An innovative approach is followed in this work in order to investigate the adsorption of dyes on activated carbon. This big internal surface makes active carbon ideal for. To study the adsorption properties of the asprepared activated carbon. Tseng rl, wu fc, juang rs 2003 liquidphase adsorption of dyes and phenols using pinewoodbased activated carbons. Adsorption isotherms, kinetics, thermodynamics and desorption. This could be related to their extended surface area, high adsorption capacity, microporous structure, and special surface reactivity. Walker b, a chemistry department, the hashemite university, p. The basics of activated carbon adsorption water tech online. Removal of dye by adsorption onto activated carbons eurasian. Adsorption of reactive dyes by palm kernel shell activated carbon.
Adsorption processes utilizing granular activated carbon gac for wastewater treatment in all these processes the wastewater is contacted with granular activated carbon gac typically in a semibatch or continuous operation. Activated carbon, agricultural wastes, surface area, wastewater treatment, adsorption. Physicochemical and adsorption studies of activated carbon. As a cationic dye, methylene blue c16h18cln3s, mb is widely used in chemical indicators, dyes and biological dyes. Freundlich constants for bb66, ab29 and dr2 dyes adsorption on activated carbon at different temperatures. Activated carbon was obtained from waste elaeagnus stone by a chemical activation method utilizing zncl2.